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Bio-molecular Functionalized Polymer Composites

     
Updated:: 2015-11-19  Clicks: 574  

Biomolecular Functionalized Polymer Composites (BFPC) Innovative Technology Team of HenanProvince

1. Introduction

BFPC is an important innovative technology team of level key disciplines in Henan province, Material science and Engineering, and based on Henan Provincial Key Laboratory of surface interface science, Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, and Henan Biological Engineering Technology Center in ZZULI. The scientific research platform possesses fixed assets with the value higher than fifty millions ¥. There are 10 members, including 6 doctors and 7 whose title is higher than Associate Professor. The main research directions mainly focus on immobilization and detection of biomolecules onto the bio-functionalized composites, the synthesis of the organic-inorganic nanocomposites and its application on the rapid quantitative detection of food additives or microbial, the fabrication of multi-funcnationlity organic-inorganic nanocomposite hydrogel and its application on heavy metal ions detection and adsorption in water or environment, and so on.

2. Group

(1) Members10

(2) Group leader: Dr. Zhihong Zhang

(3) List of group members

Names

Gender

Date of Birth

Academic   degree

Title

(Position)

Major

Research direction

Zhihong Zhang

Female

1975.06

Dr.

Associate Professor

Plasma polymerization

Biological polymer material

Yonghui Zhang

Male

1981.01

Dr.

Associate Professor

Organic chemistry

Functional material

Dongjie Guo

Male

1973.06

Dr.

Associate Professor

Inorganic chemistry

Functional material

Peiyuan Wang

Male

1979.02

Dr.

Associate Professor

Physical chemistry

Functional material

Linghao He

Female

1979.07

Dr.

Associate Professor

Polymer chemistry and Physics

Biomaterial

Long Pang

Male

1983.09

Dr.

Associate Professor

Environmental science

environmental monitoring

Xiaozhong Feng

Male

1960.08

bachelor

Professor

Material processing

Polymer material

Minghua Wang

Female

1981.10

Master

lecturer

Applied chemistry

environmental monitoring

Fufeng Yan

Male

1981.07

Master

lecturer

Material science

Polymer material

Donglai Peng

Male

1981.10

Master

lecturer

Material science

Polymer material


3. Research fields

Research direction 1Immobilization and detection of biomolecules onto the bio-functionalized composites;

Research direction 2:  Synthesis of the organic-inorganic nanocomposites and its application on the rapid quantitative detection of food additives or microbial;

Research direction 3: Fabrication of multi-funcnationlity organic-inorganic nanocomposite hydrogel and its application on heavy metal ions detection and adsorption in water or environment.

4. Research results

[Immobilization mechanism of biomolecules on plasma polymerized pyrrole] Plasma polymerized pyrrole (PPy) was prepared by the new method of plasma polymerization. On the base of the solution performance and conductivity of the developed polymer, the immobilization behavior of the biomolecules on PPy Nano film was investigated in details. Also, the anchored mechanism of DNA molecules on the surface of PPy was further probed after the detailed study of the biocompatibility of PPy.





Schematic diagram of DNA immobilization/hybridization onto plasma polymerized pyrrole and the related prize

 [Fabrication of the electrochemical biosensors based on the biomolecule-templated nanocomposites] Novel inorganic nanocomposites were prepared using one-pot method and probe molecule as template. All kinds of electrochemical approaches were applied to determine the food additives, microbial and proteins.

Schematic representation of the fabrication of Mn3(PO4)2-based biosensors for ractopamine detection.

[Basic investigation of conductive hydrogel-inorganic nanocomposites and its applications on the environmental detection] Three-dimensional conductive hydrogel nanocomposites were synthesized using pyrrole and aniline as monomer and inorganic nanomaterials as inorganic phase. On the base of the performances, the treatment ability of these new hydrogels on organic pollutants, heavy metal ions and microbial in environment was probed.




                                                                                                                                                                

Schematic diagram of the electrochemical DNA biosensor based on Cu2O@NCs nanocomposites for detecting Hg2+ ions.

Publications:

1. Minghua Wang, Shuyong Zhai, Linghao He, Donglai Peng, Xiaozhong Feng, Yanqin Yang, Shaoming Fang, Hongzhong Zhang*, Zhihong Zhang*, An electrochemical aptasensor based on TiO2/three-dimensional reduced graphene oxide/PPy nanocomposite for the sensitive detection of lysozyme, Dalton Transactions, 2015, 44,6473-6479.

2. Zhihong Zhang*, Yuanchang Zhang, Linghao He, Yanqin Yang, Shunli Liu, Minghua Wang, Shaoming Fang*, Guodong Fu, A feasible synthesis of Mn3(PO4)2@BSA nanoflowers and its application as the support nanomaterial for Pt catalyst, Journal of Power Sources, 2015,15,170-177.

3. Zhihong Zhang*, Yuanchang Zhang, Ruirui Song, Minghua Wang, Fufeng Yan, Linghao He, Xiaozhong Feng, Shaoming Fang* Jihong Zhao, Hongzhong Zhang, Manganese (II) Phosphate nanoflowers as electrochemical biosensors for the high-sensitivity detection of ractopamine, Sensors &Actuators B. Chemical, 2015, 211,310-317.

4. Shunli Liu, Mengmeng Kang, Fufeng Yan, Donglai Peng, Yanqin Yang, Linghao He, Minghua Wang, Shaoming Fang*, Zhihong Zhang*, Electrochemical DNA Biosensor Based on Microspheres of Cuprous Oxide and Nano-chitosan for Hg(II) Detection, Electrochimica Acta, 2015, 160, 64-73.

5. Mengmeng Kang, Donglai Peng, Yuanchang Zhang, Yanqin Yang, Linghao He, Fufeng Yan, Shumin Sun, Shaoming Fang, Peiyuan Wang*, Zhihong Zhang*, Electrochemical sensor rhodamine B hydrazide-immobilized graphene oxide for highly sensitive and selective detection of Cu (II), New Journal of Chemistry, 2015,39, 3137-3144.

6. Mengmeng Kang, Minghua Wang, ShuaiZhang, XiaodongDong, Linghao He, Yonghui Zhang, Dongjie Guo, Peiyuan Wang*, Shaoming Fang, Zhihong Zhang*, Highly selective and sensitive reversible sensor for Cu (II) detection based on hollow TiO2 nanospheres modified by fluorescein hydrozine-3, 6-diacetic acid, Electrochimica Acta, 2015, 161,186-194.

8. Yanqin Yang, Mengmeng Kang, Shaoming Fang, Minghua Wang, Linghao He, Jihong Zhao, Hongzhong Zhang* , Zhihong Zhang*, Electrochemical biosensor based on three-dimensional reduced graphene oxide and polyaniline nanocomposite for selective detection of mercury ions, Sensors &Actuators B. Chemical, 2015,214,63-39.

9. Zhihong Zhang, Shunli Liu, Yu Shi, et al.Label-free aptamer biosensor for thrombin detection on a nanocomposite of graphene and plasma polymerized allylamine. Journal of Materials Chemistry B, 2014, 2(11): 1530-1538.

10. Zhihong Zhang, Shunli Liu, Yuanchang Zhang, et al. Easy amino-group modification of graphene using intermolecular forces for DNA biosensing. RSC Adv. 2014, 4, 16368-16373.

11. Zhihong Zhang, Shunli Liu, Mengmeng Kang, et al. Graphene nanostructures with plasma-polymerized pyrrole as an adsorbent layer for biosensors. Microchim Acta (2014)181:1059–1067.

12. Zhihong Zhang, Shunli Liu, Yu Shi, et al. DNA Detection and Cell Adhesion on Plasma-Polymerized Pyrrole. Biopolymers, 101(5), 2013, 496-503.

13. Yong-Hui Zhang, Mei-Ling Zhang, Ye-Cheng Zhou, Ji-Hong Zhao, Shao-Ming Fang, and Feng Li, Tunable electronic and magnetic properties of graphene-like ZnO monolayer upon doping and CO adsorption: a first-principles study, J. Mater. Chem. A 2014,2,13129-13135.

14. Yong-Hui Zhang, Li-Feng Han, Yuan-Hua Xiao,Dian-Zeng Jia, Zhan-Hu Guo,Feng Li, Understanding dopant and defect effect on H2S sensing performances of graphene: a first-principles study, Comput. Mater. Sci. 2013, 69, 222-228.

15. Dong-Jie Guo, Hao Zhang, Shao-Ming Fang, et al. Fabrication and adhesion of bio-inspired seta: Capillarity-induced casting of porous silicon, Journal of Materials Chemistry B, 2013, 1, 379-386.

16. Linghao He, Jing Sun, Xiuxin Wang, et al. Facile and effective promotion of β crystalline phase in poly(vinylidene fluoride) via the incorporation of imidazolium ionic liquids. Polymer International, 2013, 62: 638-646.

17.Linghao He, Guangmei Xia, Jing Sun, et al. Unzipped multiwalled carbon nanotubes-incorporated poly(vinylidene fluoride) nanocomposites with enhanced interface and piezoelectric b phase. Journal of Colloid and Interface Science, 2013, 393: 97–103.

18. Long pang, Jingfu Liu, Yongguang Yin, Mohai Shen, Evaluating the sorption of organophosphate esters to different sourced humic acide and its effects on the toxicity todaphnia magna Environmental Toxicology and Chemistry, 2013, 32, 2755-2761.


5. Research projects

Order

Title

Project source

Project No.

project leader

Grants (Ten thousand Yuan)

Period

1

Nanocomposite of functionalized graphene and polymer and its application as biosensors

The national natural science foundation

51173172

Zhihong Zhang

60

2012.01-2015.12

2

Functionalized self-assembled graphene   film and its application on rapidly quantitative detection of food additives

Science and Technology Opening   Cooperation Project of HenanProvince

132106000076

Zhihong Zhang

30

2015.01-2016.12

3

The design of new heterocyclic covalent organic network material   synthesis and structure-activity relationship study

The national natural science foundation

21104070

Peiyuan Wang

25

2012.01-2014.12

4

Band control and biosensing mechanism of functionalized grapghene

The national natural science foundation

21301158

Yonghui Zhang

28

2014.01-2016.12

5

Fabrication of high performance long-life   ionic electric actuator

The ministry of education

132106000076

Dongjie Guo

3.5

2013.01-2014.12

6

Polymer-modified carbon nanotubes and   their electrochemical behavior of load catalyst particles

Henan province education department

14A150003

Linghao He

3

2014.01-2016

7

functional design of zinc oxide Gas   sensors

Technology bureau of Zhengzhou jinshui

Jinke (2012)23-17

Yonghui Zhang

5

2013.01-2014.12


6. Photos







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